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KMID : 0604520020280010214
Journal of the Society of Cosmetic Scientists of Korea
2002 Volume.28 No. 1 p.214 ~ p.324
Synthesis of High Concentrated TiO©üNano Colloids and Coating on Boron Nitride Powders
HYEIN JANG
KYUNGCHULLEE/SUNGHO HONG/HONGKEUN JI
Abstract
High concentrated TiO©ünano colloids were synthesized by sol-gel method. Reactions were performed in TiC1©þ/HC1/H©üO aqueous solution and the conditions of particles such as shape, size and aggregation, etc. were controlled by polymerization and adsorption of acrylamide in surface of TiO©ü nano particles. And also, aminopropyltriethoxysilane was added instead of acrylamide and compared each other. The prepared colloids were well dispersed and showed the strong absorption peaks at 350nm-370nm which is blue shifted to 20-30nm, compared to macro particles. The obtained techniques from TiO©ünato colloids synthesis were utilized in coating on boron nitride powders which are nonpolar and isoelectronic materials of carbon. Their surface morphology, structure, thermal stability and U. V absorption chracteristics were examined by SEM(Scanning Electron Microscopy), XRD(X-ray diffraction), TG/DTA(Thermogravimetric and Differential Thermal Analysis), UV-VIS(Ultraviolet-Visible Spectroscopy).
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